Issue 37, 2005

Carboxylate complexation by 1,1′-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state

Abstract

A simple bis-urea containing anion receptor, synthesised from ortho-phenylenediamine, has been shown to have excellent selectivity for carboxylates in solution, with a crystal structure elucidation of the benzoate complex showing four hydrogen bonds between the receptor and anion in the solid state.

Graphical abstract: Carboxylate complexation by 1,1′-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state

Supplementary files

Article information

Article type
Communication
Submitted
08 Jun 2005
Accepted
02 Aug 2005
First published
22 Aug 2005

Chem. Commun., 2005, 4696-4698

Carboxylate complexation by 1,1′-(1,2-phenylene)bis(3-phenylurea) in solution and the solid state

S. J. Brooks, P. A. Gale and M. E. Light, Chem. Commun., 2005, 4696 DOI: 10.1039/B508144K

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