Issue 33, 2005
From the journal:

Chemical Communications

Novel HEXOL-type cyclometallated iridium(iii) complexes: stereoselective synthesis and structure elucidation†

Liangru Yang,a   Alex von Zelewsky*a  and  Helen Stoeckli-Evansb  

* Corresponding authors

a Department of Chemistry, University of Fribourg, Pérolles, 1700 Fribourg, Switzerland
E-mail: Alexander.vonzelewsky@unifr.ch
Fax: +41 26 3009738
Tel: +41 26 3008732

b Institute of Chemistry, University of Neuchâtel, Avenue de Bellevaux 51, 2007 Neuchâtel, Switzerland
E-mail: Helen.Stoeckli-Evans@unine.ch
Fax: + 41 32 7182511
Tel: + 41 32 7182426

Abstract

Two diastereoisomers of tetranuclear cyclometallated iridium complexes, either having an inner core of HEXOL-type [Ir(IrCl2)3]6+ unit and a surface of six chiral, didentate, cyclometallated ligands, are stereoselectively synthesized from an enantiopure pinenopyridine derivative.

Graphical abstract: Novel HEXOL-type cyclometallated iridium(iii) complexes: stereoselective synthesis and structure elucidation

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Article information

DOI
https://doi.org/10.1039/B507769A
Article type
Communication
Submitted
03 Jun 2005
Accepted
30 Jun 2005
First published
28 Jul 2005

Chem. Commun., 2005, 4155-4157

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Novel HEXOL-type cyclometallated iridium(III) complexes: stereoselective synthesis and structure elucidation

L. Yang, A. von Zelewsky and H. Stoeckli-Evans, Chem. Commun., 2005, 4155 DOI: 10.1039/B507769A

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