Issue 32, 2005
From the journal:

Chemical Communications

Ru(iv)-catalyzed isomerization of allylamines in water: A highly efficient procedure for the deprotection of N-allylic amines

Victorio Cadierno,*a   Sergio E. García-Garrido,a   José Gimeno*a  and  Noel Nebraa  

* Corresponding authors

a Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica “Enrique Moles” (Unidad Asociada al C.S.I.C.), Universidad de Oviedo, Oviedo, Spain
E-mail: jgh@uniovi.es (José Gimeno); vcm@uniovi.es (Victorio Cadierno)
Fax: +34985103446
Tel: +34985103461

Abstract

A general and efficient method for the deprotection of N-allylic substrates in aqueous media, using catalytic amounts of the bis(allyl)-ruthenium(IV) complexes [Ru(η3 ∶ η2 ∶ η3-C12H18)Cl2] (1) and [{Ru(η3 ∶ η3-C10H16)(μ-Cl)Cl}2] (2), has been developed.

Graphical abstract: Ru(iv)-catalyzed isomerization of allylamines in water: A highly efficient procedure for the deprotection of N-allylic amines

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Article information

DOI
https://doi.org/10.1039/B506788J
Article type
Communication
Submitted
13 May 2005
Accepted
22 Jun 2005
First published
13 Jul 2005

Chem. Commun., 2005, 4086-4088

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Ru(IV)-catalyzed isomerization of allylamines in water: A highly efficient procedure for the deprotection of N-allylic amines

V. Cadierno, S. E. García-Garrido, J. Gimeno and N. Nebra, Chem. Commun., 2005, 4086 DOI: 10.1039/B506788J

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