Issue 29, 2005

The bis-molybdenum(0) trianion [1,3,6-{Mo(CO)3}-3,6-(μ-H)2-1,1,1-(CO)3-2-Ph-closo-1,2-MoCB9H7]3− and its use as a scaffold in the assembly of heteropolymetallic complexes

Abstract

The title trianion reacts successively with cationic transition-metal fragments to afford a heterotrimetallic Mn–Mo–Pt species.

Graphical abstract: The bis-molybdenum(0) trianion [1,3,6-{Mo(CO)3}-3,6-(μ-H)2-1,1,1-(CO)3-2-Ph-closo-1,2-MoCB9H7]3− and its use as a scaffold in the assembly of heteropolymetallic complexes

Supplementary files

Article information

Article type
Communication
Submitted
27 Apr 2005
Accepted
18 May 2005
First published
13 Jun 2005

Chem. Commun., 2005, 3706-3708

The bis-molybdenum(0) trianion [1,3,6-{Mo(CO)3}-3,6-(μ-H)2-1,1,1-(CO)3-2-Ph-closo-1,2-MoCB9H7]3− and its use as a scaffold in the assembly of heteropolymetallic complexes

P. Lei, T. D. McGrath and F. G. A. Stone, Chem. Commun., 2005, 3706 DOI: 10.1039/B505841D

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