Issue 36, 2005

Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation

Abstract

A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)FeIII–O2]+, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [FeII(TMC)]2+, and molecular oxygen is reported as well.

Graphical abstract: Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation

Supplementary files

Article information

Article type
Communication
Submitted
21 Apr 2005
Accepted
21 Jul 2005
First published
10 Aug 2005

Chem. Commun., 2005, 4529-4531

Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation

J. Annaraj, Y. Suh, M. S. Seo, S. O. Kim and W. Nam, Chem. Commun., 2005, 4529 DOI: 10.1039/B505562H

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