Issue 27, 2005
From the journal:

Chemical Communications

Enantioselective hydrogenation of alkenes and imines by a gold catalyst

Camino González-Arellano,ac   Avelino Corma,*b   Marta Iglesiasc  and  Felix Sáncheza  

* Corresponding authors

a Instituto de Química Orgánica General, CSIC, C/Juan de la Cierva 3, 28006 Madrid, Spain
E-mail: felix-iqo@iqog.csic.es
Fax: +34915644872

b Instituto de Tecnología Química, UPV-CSIC, Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain
E-mail: acorma@itq.upv.es
Fax: +34963877809

c Instituto de Ciencia de Materiales de Madrid, CSIC, C/Sor Juana Inés de la Cruz, s/n Cantoblanco, 28049 Madrid, Spain
E-mail: marta.iglesias@icmm.csic.es
Fax: +34913720623

Abstract

A new neutral dimeric gold(I) complex bearing the 1,2-bis[(2R,5R)-2,5-dimethylphospholanebenzene] [(R,R)-Me-Duphos] ligand has been synthesized which catalyzes the asymmetric hydrogenation of alkenes and imines under mild reaction conditions.

Graphical abstract: Enantioselective hydrogenation of alkenes and imines by a gold catalyst

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Article information

DOI
https://doi.org/10.1039/B505271H
Article type
Communication
Submitted
14 Apr 2005
Accepted
18 May 2005
First published
09 Jun 2005

Chem. Commun., 2005, 3451-3453

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Enantioselective hydrogenation of alkenes and imines by a gold catalyst

C. González-Arellano, A. Corma, M. Iglesias and F. Sánchez, Chem. Commun., 2005, 3451 DOI: 10.1039/B505271H

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