Eu8(NCN)5−δI6+2δ				(δ				= 0.05): a novel rare-earth carbodiimide iodide containing oligomeric tritetrahedral Eu8 clusters

Wuping Liao; Boniface P. T. Fokwa; Richard Dronskowski

doi:10.1039/B504235F

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Eu₈(NCN)_5−δI_6+2δ (δ = 0.05): a novel rare-earth carbodiimide iodide containing oligomeric tritetrahedral Eu₈ clusters†

Wuping Liao,^a Boniface P. T. Fokwa^a and Richard Dronskowski*^a

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* Corresponding authors

^a Institut für Anorganische Chemie der RWTH Aachen, Landoltweg 1, D-52056 Aachen, Germany
E-mail: drons@HAL9000.ac.rwth-aachen.de
Fax: +49-241-80 92642
Tel: +49-241-80 93642

Abstract

Eu₈(NCN)_4.95I_6.10 is the first compound with discrete tritetrahedral Eu₈ clusters which are interconnected by coordinating NCN²⁻ carbodiimide anions on their triangular faces to form separated layers, the latter being bridged by iodide and carbodiimide anions.

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Article information

DOI: https://doi.org/10.1039/B504235F
Article type: Communication
Submitted: 29 Mar 2005
Accepted: 16 May 2005
First published: 09 Jun 2005

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Chem. Commun., 2005, 3612-3614

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Eu₈(NCN)_5−δI_6+2δ (δ = 0.05): a novel rare-earth carbodiimide iodide containing oligomeric tritetrahedral Eu₈ clusters

W. Liao, B. P. T. Fokwa and R. Dronskowski, Chem. Commun., 2005, 3612 DOI: 10.1039/B504235F

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