Issue 24, 2005

Titanium-mediated [4 + 1] assembly of 1,3-dienes and nitriles: formation of 3-cyclopentenyl amines and cyclopentenones

Abstract

In the presence of Ti(OiPr)4 and iPrMgCl, dienes couple with nitriles to afford the title products in good yields.

Graphical abstract: Titanium-mediated [4 + 1] assembly of 1,3-dienes and nitriles: formation of 3-cyclopentenyl amines and cyclopentenones

Article information

Article type
Communication
Submitted
11 Mar 2005
Accepted
03 May 2005
First published
24 May 2005

Chem. Commun., 2005, 3030-3032

Titanium-mediated [4 + 1] assembly of 1,3-dienes and nitriles: formation of 3-cyclopentenyl amines and cyclopentenones

C. Laroche, P. Bertus and J. Szymoniak, Chem. Commun., 2005, 3030 DOI: 10.1039/B503643G

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