Issue 22, 2005
From the journal:

Chemical Communications

A new mechanism for nucleophilic substitution at a thiophosphoryl centre revealed by the reaction of diisopropylamine with PSCl3

Martin J. P. Hargera  

a Department of Chemistry, University of Leicester, Leicester, LE1 7RH
E-mail: mjph2@le.ac.uk
Fax: +44(0)116 2523789
Tel: +44(0)116 2522127

Abstract

The reaction of PSCl3 with Pri2NH at 60 °C affords the disubstitution product (Pri2N)2P(S)Cl without first forming the monosubstitution product Pri2NP(S)Cl2; a PIII compound (possibly PCl3) generated in situ seems to be a crucial intermediate.

Graphical abstract: A new mechanism for nucleophilic substitution at a thiophosphoryl centre revealed by the reaction of diisopropylamine with PSCl3

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Article information

DOI
https://doi.org/10.1039/B502615F
Article type
Communication
Submitted
24 Feb 2005
Accepted
07 Apr 2005
First published
22 Apr 2005

Chem. Commun., 2005, 2863-2865

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A new mechanism for nucleophilic substitution at a thiophosphoryl centre revealed by the reaction of diisopropylamine with PSCl3

M. J. P. Harger, Chem. Commun., 2005, 2863 DOI: 10.1039/B502615F

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