Issue 20, 2005
From the journal:

Chemical Communications

Carbon–nitrogen bond cleavage in pyridine ring systems mediated by organometallic thorium(iv) complexes†

Jaime A. Pool,a   Brian L. Scotta  and  Jaqueline L. Kiplinger*a  

* Corresponding authors

a Chemistry Division, Los Alamos National Laboratory, Los Alamos, USA
E-mail: kiplinger@lanl.gov
Fax: (505)667-9905
Tel: (505)665-9553

Abstract

Thorium(IV) alkyl and aryl complexes of the type (C5Me5)2ThR2 (R = CH2Ph, Ph) have been found to mediate the facile ring-opening and dearomatization of the pyridine ring of pyridine N-oxide under ambient conditions to afford the first thorium η2-(O,N)-oximate complexes.

Graphical abstract: Carbon–nitrogen bond cleavage in pyridine ring systems mediated by organometallic thorium(iv) complexes

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Article information

DOI
https://doi.org/10.1039/B502439K
Article type
Communication
Submitted
15 Feb 2005
Accepted
22 Mar 2005
First published
11 Apr 2005

Chem. Commun., 2005, 2591-2593

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Carbon–nitrogen bond cleavage in pyridine ring systems mediated by organometallic thorium(IV) complexes

J. A. Pool, B. L. Scott and J. L. Kiplinger, Chem. Commun., 2005, 2591 DOI: 10.1039/B502439K

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