Issue 20, 2005

The rhodium catalyzed three-component reaction of diazoacetates, titanium(iv) alkoxides and aldehydes

Abstract

The rhodium(II)-catalyzed three-component reaction of diazoacetates, titanium alkoxides and aldehydes is shown to give α-alkoxyl-β-hydroxyl acid derivatives; the novel C–C bond formation reaction is proposed to occur through oxonium ylides derived from diazo compounds and titanium alkoxides, and followed by intermolecular trapping by aldehydes.

Graphical abstract: The rhodium catalyzed three-component reaction of diazoacetates, titanium(iv) alkoxides and aldehydes

Supplementary files

Article information

Article type
Communication
Submitted
10 Feb 2005
Accepted
22 Mar 2005
First published
06 Apr 2005

Chem. Commun., 2005, 2624-2626

The rhodium catalyzed three-component reaction of diazoacetates, titanium(IV) alkoxides and aldehydes

C. Lu, H. Liu, Z. Chen, W. Hu and A. Mi, Chem. Commun., 2005, 2624 DOI: 10.1039/B502093J

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