Issue 17, 2005
From the journal:

Chemical Communications

A unique site-selective reaction of ketones with new recyclable hypervalent iodine(iii) reagents based on a tetraphenylmethane structure†

Toshifumi Dohi,a   Akinobu Maruyama,a   Misaki Yoshimura,a   Koji Morimoto,a   Hirofumi Tohma,a   Motoo Shirob  and  Yasuyuki Kita*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka, Japan
E-mail: kita@phs.osaka-u.ac.jp
Fax: +81-6-6879-8229
Tel: +81-6-6879-8225

b Rigaku Corporation, 3-9-12 Matsubara, Akishima, Tokyo, Japan

Abstract

We have synthesized new recyclable reagents having a tetraphenylmethane backbone and used them in the site-selective α-tosyloxylation of ketones.

Graphical abstract: A unique site-selective reaction of ketones with new recyclable hypervalent iodine(iii) reagents based on a tetraphenylmethane structure

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Article information

DOI
https://doi.org/10.1039/B501475A
Article type
Communication
Submitted
31 Jan 2005
Accepted
25 Feb 2005
First published
16 Mar 2005

Chem. Commun., 2005, 2205-2207

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A unique site-selective reaction of ketones with new recyclable hypervalent iodine(III) reagents based on a tetraphenylmethane structure

T. Dohi, A. Maruyama, M. Yoshimura, K. Morimoto, H. Tohma, M. Shiro and Y. Kita, Chem. Commun., 2005, 2205 DOI: 10.1039/B501475A

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