Issue 21, 2005

The synthesis of a sterically hindered samarium(ii) bis(amidinate) and conversion to its homoleptic trivalent congener

Abstract

The first divalent samarium bis(amidinate) has been prepared and aspects of its novel chemistry, including the preparation of a sterically hindered homoleptic Sm(III) tris(amidinate), explored.

Graphical abstract: The synthesis of a sterically hindered samarium(ii) bis(amidinate) and conversion to its homoleptic trivalent congener

Supplementary files

Article information

Article type
Communication
Submitted
28 Jan 2005
Accepted
17 Mar 2005
First published
07 Apr 2005

Chem. Commun., 2005, 2695-2697

The synthesis of a sterically hindered samarium(II) bis(amidinate) and conversion to its homoleptic trivalent congener

M. L. Cole and P. C. Junk, Chem. Commun., 2005, 2695 DOI: 10.1039/B501447F

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