Cp*(iPr3P)Ru(Cl)(η2-HSiClMe2): the first complex with simultaneous Si–H and RuCl⋯SiCl inter-ligand interactions†
Abstract
The addition of HSiMe2Cl to the unsaturated compound Cp*(iPr3P)RuCl gives an unstable adduct which, according to
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* Corresponding authors
a
Chemistry Department, Moscow State University, Vorob'evy Gory, Moscow, Russia
E-mail:
nikonov@org.chem.msu.ru
Fax: +7 (095) 9328846
Tel: +7 (095) 9391976
b
Institut de Química Computacional, Campus de Montilivi, Universitat de Girona, Girona, Catalonia, Spain
E-mail:
vybo@stark.udg.es
Fax: +34 97241 8356
Tel: +34 97241 8362
c
Institute of General and Inorganic Chemistry RAS, Leninskii Prosp. 31, Moscow, Russia
E-mail:
kuzmina@igic.ras.ru
Fax: +7 (095) 9541279
Tel: +7 (095) 9521803
d
Chemistry Department, University of Durham, South Road, Durham, UK
E-mail:
j.a.k.howard@durham.ac.uk
Fax: +44 (0)191 384 4737
Tel: +44 (0)191 374 4647
The addition of HSiMe2Cl to the unsaturated compound Cp*(iPr3P)RuCl gives an unstable adduct which, according to
A. L. Osipov, S. F. Vyboishchikov, K. Y. Dorogov, L. G. Kuzmina, J. A. K. Howard, D. A. Lemenovskii and G. I. Nikonov, Chem. Commun., 2005, 3349 DOI: 10.1039/B500679A
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