Issue 17, 2005

Tandem oxidation processes: a combined phosphorus- and sulfur-ylide approach to polysubstituted cyclopropanes

Abstract

A new manganese dioxide-mediated tandem oxidation process (TOP) has been developed which, by suitable combination of stabilised phosphorus- and sulfur-ylides, allows the direct conversion of allylic alcohols or α-hydroxyketones into polysubstituted cyclopropanes.

Graphical abstract: Tandem oxidation processes: a combined phosphorus- and sulfur-ylide approach to polysubstituted cyclopropanes

Article information

Article type
Communication
Submitted
13 Jan 2005
Accepted
24 Feb 2005
First published
14 Mar 2005

Chem. Commun., 2005, 2253-2255

Tandem oxidation processes: a combined phosphorus- and sulfur-ylide approach to polysubstituted cyclopropanes

M. F. Oswald, S. A. Raw and R. J. K. Taylor, Chem. Commun., 2005, 2253 DOI: 10.1039/B500396B

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