Issue 13, 2005
From the journal:

Chemical Communications

Tuning of spin crossover equilibrium in catecholatoiron(iii) complexes by supporting ligands†

Yutaka Hitomi,*a   Masakazu Higuchi,a   Hisataka Minami,a   Tsunehiro Tanakaa  and  Takuzo Funabiki*b  

* Corresponding authors

a Department of Molecular Engineering, Kyoto University, Kyoto Daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: hitomi@moleng.kyoto-u.ac.jp
Fax: 81 75 383 2561
Tel: 81 75 383 2562

b Biomimetics Research Center, Doshisha University, Kyo-Tanabe, Kyoto 610-0321, Japan
E-mail: funabiki@scl.kyoto-u.ac.jp

Abstract

Introduction of electron-withdrawing groups on co-ligands effectively raises the spin crossover temperature of catecholatoiron(III) complexes and induces a significant amount of the low spin species in solution even at around room temperature.

Graphical abstract: Tuning of spin crossover equilibrium in catecholatoiron(iii) complexes by supporting ligands

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Article information

DOI
https://doi.org/10.1039/B418678H
Article type
Communication
Submitted
14 Dec 2004
Accepted
25 Jan 2005
First published
02 Feb 2005

Chem. Commun., 2005, 1758-1760

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Tuning of spin crossover equilibrium in catecholatoiron(III) complexes by supporting ligands

Y. Hitomi, M. Higuchi, H. Minami, T. Tanaka and T. Funabiki, Chem. Commun., 2005, 1758 DOI: 10.1039/B418678H

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