Issue 18, 2005
From the journal:

Chemical Communications

Supramolecular isomers in the same crystal: a new type of entanglement involving ribbons of rings and 2D (4,4) networks polycatenated in a 3D architecture†

Baolong Li,*a   Yanfen Peng,a   Baozong Lia  and  Yong Zhanga  

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou, P. R. China
E-mail: blli1965@pub.sz.jsinfo.net

Abstract

The reaction of corresponding cadmium salts with the flexible ligand 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene (bbtz) affords the 3D coordination network [Cd3(bbtz)6(H2O)6](BF4)6·1.75H2O (1), containing ribbons of rings and planar 2D (4,4) networks polycatenated with each other, the undulating 2D (4,4) network [Cd(bbtz)2(H2O)2](ClO4)2·2H2O (2), and ribbons of rings [Cd(bbtz)2(H2O)2](BF4)2·3DMF (3) and [Cd(bbtz)2(H2O)2](ClO4)2·3DMF (4).

Graphical abstract: Supramolecular isomers in the same crystal: a new type of entanglement involving ribbons of rings and 2D (4,4) networks polycatenated in a 3D architecture

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Article information

DOI
https://doi.org/10.1039/B418392D
Article type
Communication
Submitted
09 Dec 2004
Accepted
07 Mar 2005
First published
18 Mar 2005

Chem. Commun., 2005, 2333-2335

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Supramolecular isomers in the same crystal: a new type of entanglement involving ribbons of rings and 2D (4,4) networks polycatenated in a 3D architecture

B. Li, Y. Peng, B. Li and Y. Zhang, Chem. Commun., 2005, 2333 DOI: 10.1039/B418392D

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