Issue 14, 2005
From the journal:

Chemical Communications

Regioselective allylgallation of terminal alkynes

Phil Ho Lee,*a   Yunkiu Heo,a   Dong Seomoon,a   Sundae Kima  and  Kooyeon Leea  

* Corresponding authors

a Department of Chemistry, Kangwon National University, Chunchon 200-701, Republic of Korea
E-mail: phlee@kangwon.ac.kr
Fax: +82 33 253 7582
Tel: +82 33 250 8493

Abstract

The reactions of terminal alkynes with allylgallium reagents generated in situ from gallium and allyl bromides gave the corresponding 1,4-dienes in good yield via Markovnikov addition in THF at 70 °C.

Graphical abstract: Regioselective allylgallation of terminal alkynes

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Article information

DOI
https://doi.org/10.1039/B417975G
Article type
Communication
Submitted
30 Nov 2004
Accepted
27 Jan 2005
First published
09 Feb 2005

Chem. Commun., 2005, 1874-1876

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Regioselective allylgallation of terminal alkynes

P. H. Lee, Y. Heo, D. Seomoon, S. Kim and K. Lee, Chem. Commun., 2005, 1874 DOI: 10.1039/B417975G

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