Issue 12, 2005

Spontaneous resolution in a halogen bonded supramolecular architecture

Abstract

The halogen bonding driven self-assembly of 1,8-diiodoperfluorooctane and N,N,N′,N′-tetramethyl-p-phenylenediamine induces the formation of a chiral and enantiopure co-crystal wherein the fluorinated chains adopt an unusual gauche arrangement.

Graphical abstract: Spontaneous resolution in a halogen bonded supramolecular architecture

Supplementary files

Article information

Article type
Communication
Submitted
25 Nov 2004
Accepted
07 Jan 2005
First published
27 Jan 2005

Chem. Commun., 2005, 1534-1536

Spontaneous resolution in a halogen bonded supramolecular architecture

H. Neukirch, E. Guido, R. Liantonio, P. Metrangolo, T. Pilati and G. Resnati, Chem. Commun., 2005, 1534 DOI: 10.1039/B417771A

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