Unique adsorption behavior of H2 and CO over group 8–10 metals encapsulated inside silica nanotubes and nanocapsules

Shuichi Naito; Masato Ue; Seiko Sakai; Toshihiro Miyao

doi:10.1039/B417396A

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Unique adsorption behavior of H₂ and CO over group 8–10 metals encapsulated inside silicananotubes and nanocapsules

Shuichi Naito,*^a Masato Ue,^a Seiko Sakai^a and Toshihiro Miyao^a

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* Corresponding authors

^a Department of Applied Chemistry, Kanagawa University, 3-27-1, Rokkakubashi, Kanagawa-ku, Yokohama, Japan
E-mail: naitos01@kanagawa-u.ac.jp
Fax: +81 45 413 9770
Tel: +81 45 481 5661

Abstract

Various silica nanotubes and nanocapsules have been prepared successfully, possessing unique silica walls of selective H₂ permeation and encapsulate group 8–10 metal particles inside and exhibit a marked stabilization effect of H₂ and CO over the metals in the network of silica wall and inside nanoscale cavities.

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Article information

DOI: https://doi.org/10.1039/B417396A
Article type: Communication
Submitted: 18 Nov 2004
Accepted: 05 Jan 2005
First published: 26 Jan 2005

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Chem. Commun., 2005, 1563-1565

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Unique adsorption behavior of H₂ and CO over group 8–10 metals encapsulated inside silica nanotubes and nanocapsules

S. Naito, M. Ue, S. Sakai and T. Miyao, Chem. Commun., 2005, 1563 DOI: 10.1039/B417396A

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Chemical Communications