Issue 9, 2005

A new type of nonsulfide hydrotreating catalyst: nickel phosphide on carbon

Abstract

Nickel phosphide on carbon is successfully synthesized by temperature-programmed reduction as verified with X-ray diffraction and extended X-ray absorption fine structure measurements; it shows superior activity, selectivity, and stability for sulfur removal from the refractory compound 4,6-dimethyldibenzothiophene with a steady-state conversion of 99%, which is much higher than that of a commercial NiMoS/γ-Al2O3 catalyst of 68%.

Graphical abstract: A new type of nonsulfide hydrotreating catalyst: nickel phosphide on carbon

Article information

Article type
Communication
Submitted
14 Oct 2004
Accepted
22 Nov 2004
First published
12 Jan 2005

Chem. Commun., 2005, 1143-1145

A new type of nonsulfide hydrotreating catalyst: nickel phosphide on carbon

Y. Shu and S. T. Oyama, Chem. Commun., 2005, 1143 DOI: 10.1039/B415838E

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