Issue 26, 2005

The influence of sterics on the formation of polar 1-D hydrogen-bonded networks

Abstract

Polar, noncentrosymmetric packing of directional, 1-D hydrogen-bonded networks of chiral, 4-amino-2,6-bis(oxazolinyl)pyridines (ampybox) occurs for isopropyl-substituted ampybox 2; in contrast, 1-D networks of methyl-substituted ampybox 1 pack in an antiparallel arrangement.

Graphical abstract: The influence of sterics on the formation of polar 1-D hydrogen-bonded networks

Supplementary files

Article information

Article type
Communication
Submitted
17 Sep 2004
Accepted
02 May 2005
First published
25 May 2005

Chem. Commun., 2005, 3280-3282

The influence of sterics on the formation of polar 1-D hydrogen-bonded networks

A. J. Preston, J. C. Gallucci and J. R. Parquette, Chem. Commun., 2005, 3280 DOI: 10.1039/B414470H

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