Issue 5, 2005
From the journal:

Chemical Communications

Direct mono-insertion of isocyanides into terminal alkynes catalyzed by rare-earth silylamides†

Kimihiro Komeyama,*a   Daisuke Sasayama,a   Tomonori Kawabata,a   Katsuomi Takehiraa  and  Ken Takakia  

* Corresponding authors

a Department of Chemistry and Chemical Engineering, Graduate School of Engineering, Hiroshima University, Kagamiyama, Higashi-Hiroshima, Japan
E-mail: kkome@hiroshima-u.ac.jp
Fax: +81 82 424 5494
Tel: +81 82 424 7738

Abstract

Rare-earth silylamide complexes, Ln[N(SiMe3)2]3 (Ln = Y, La, Sm, Yb), effectively catalyzed the coupling reaction of isocyanides with both aliphatic and aromatic terminal alkynes under mild conditions.

Graphical abstract: Direct mono-insertion of isocyanides into terminal alkynes catalyzed by rare-earth silylamides

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Article information

DOI
https://doi.org/10.1039/B414302G
Article type
Communication
Submitted
17 Sep 2004
Accepted
26 Oct 2004
First published
13 Dec 2004

Chem. Commun., 2005, 634-636

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Direct mono-insertion of isocyanides into terminal alkynes catalyzed by rare-earth silylamides

K. Komeyama, D. Sasayama, T. Kawabata, K. Takehira and K. Takaki, Chem. Commun., 2005, 634 DOI: 10.1039/B414302G

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