Issue 3, 2005
From the journal:

Chemical Communications

Rh(ii) catalysed intramolecular C–H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse†

Nuno R. Candeias,a   Pedro M. P. Goisa  and  Carlos A. M. Afonso*b  

* Corresponding authors

a REQUIMTE/CQFB, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Caparica, Portugal

b CQFM, Departmento de Engenharia Química, Instituto Superior Técnico, Lisboa, Portugal
E-mail: carlosafonso@ist.utl.pt
Fax: + 351 21 8417122
Tel: + 351 21 8417627

Abstract

Water is an efficient solvent for the Rh2(OAc)4 catalysed intramolecular C–H insertion of a range of diazo substrates without competitive water insertion. Due to the high solubility and stability of the catalyst in water, the catalyst can be efficiently reused.

Graphical abstract: Rh(ii) catalysed intramolecular C–H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse

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Article information

DOI
https://doi.org/10.1039/B414233K
Article type
Communication
Submitted
16 Sep 2004
Accepted
16 Nov 2004
First published
10 Dec 2004

Chem. Commun., 2005, 391-393

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Rh(II) catalysed intramolecular C–H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse

N. R. Candeias, P. M. P. Gois and C. A. M. Afonso, Chem. Commun., 2005, 391 DOI: 10.1039/B414233K

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