Issue 6, 2005
From the journal:

Chemical Communications

Chemiluminescence in molecular recognition: base-induced decomposition of optically active dioxetanes bearing a bisnaphthol moiety with a complex of optically active crown ether–potassium tert-butoxide†

Masakatsu Matsumoto,*a   Koji Hamaoka,a   Yuji Takashima,a   Mizuki Yokokawa,a   Kazutaka Yamada,a   Nobuko Watanabea  and  Hisako K. Ijuina  

* Corresponding authors

a Department of Materials Science, Kanagawa University, Tsuchiya, Hiratsuka, Kanagawa 259-1293, Japan
E-mail: matsumo-chem@kanagawa-u.ac.jp

Abstract

Four optically pure isomers of dioxetane (1) were decomposed by the action of the complex of an optically active crown ether with potassium tert-butoxide to afford light with λmaxCL and gave four different spectrum shapes.

Graphical abstract: Chemiluminescence in molecular recognition: base-induced decomposition of optically active dioxetanes bearing a bisnaphthol moiety with a complex of optically active crown ether–potassium tert-butoxide

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Article information

DOI
https://doi.org/10.1039/B414001J
Article type
Communication
Submitted
13 Sep 2004
Accepted
15 Nov 2004
First published
23 Dec 2004

Chem. Commun., 2005, 808-810

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Chemiluminescence in molecular recognition: base-induced decomposition of optically active dioxetanes bearing a bisnaphthol moiety with a complex of optically active crown ether–potassium tert-butoxide

M. Matsumoto, K. Hamaoka, Y. Takashima, M. Yokokawa, K. Yamada, N. Watanabe and H. K. Ijuin, Chem. Commun., 2005, 808 DOI: 10.1039/B414001J

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