A parallel, offset-stacked orientation was found in the crystal packing of E,E-1,4-di(o-trifluoromethyl)phenyl-1,3-butadiene. UV-irradiation of the powered crystalline sample resulted in a quantitative conversion to a single [2 + 2] cycloaddition product.
J. Liu and K. J. Boarman, Chem. Commun., 2005, 340 DOI: 10.1039/B413898H
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