Issue 3, 2005
From the journal:

Chemical Communications

Novel electron-transfer oxidation of Lipshutz cuprates with 1,4-benzoquinones: an efficient homo-coupling reaction of aryl halides and its application to the construction of macrocyclic systems

Yoshihiro Miyake,a   Mo Wu,a   M. Jalilur Rahmana  and  Masahiko Iyoda*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Japan
E-mail: iyoda-masahiko@c.metro-u.ac.jp
Fax: +81-426-77-2525

Abstract

The electron transfer reaction from Lipshutz cuprates, which can be easily prepared from aryl bromides, to 1,4-benzoquinones was found to proceed smoothly, affording either the corresponding homo-coupling products, in modest to excellent yields, or macrocyclic products selectively.

Graphical abstract: Novel electron-transfer oxidation of Lipshutz cuprates with 1,4-benzoquinones: an efficient homo-coupling reaction of aryl halides and its application to the construction of macrocyclic systems

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Article information

DOI
https://doi.org/10.1039/B413842B
Article type
Communication
Submitted
09 Sep 2004
Accepted
25 Oct 2004
First published
01 Dec 2004

Chem. Commun., 2005, 411-413

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Novel electron-transfer oxidation of Lipshutz cuprates with 1,4-benzoquinones: an efficient homo-coupling reaction of aryl halides and its application to the construction of macrocyclic systems

Y. Miyake, M. Wu, M. J. Rahman and M. Iyoda, Chem. Commun., 2005, 411 DOI: 10.1039/B413842B

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