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cis-Vinylic aziridines were prepared highly stereoselectively via a NaI-catalyzed regioselective ring-opening [1 + 2] cycloaddition reaction of cyclopropenes with imines.

Graphical abstract: NaI-catalyzed highly regioselective ring-opening [1 + 2] cycloaddition reaction of cyclopropenes with imines: highly stereoselective synthesis of cis-vinylic aziridines

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