Issue 6, 2005
From the journal:

Chemical Communications

Synthesis and characterisation of two monomeric crystalline thallium(i) β-diketiminates†

Yanxiang Cheng,a   Peter B. Hitchcock,a   Michael F. Lappert*a  and  Meisu Zhoua  

* Corresponding authors

a Chemistry Department, University of Sussex, Brighton, UK
E-mail: m.f.lappert@sussex.ac.uk

Abstract

Treatment of the appropriate sodium β-diketiminate NaL or NaL′ with an equivalent portion of TlCl in thf under mild conditions furnishes in good yield the first structurally characterised thallium β-diketiminates: the monomeric, orange, crystalline Tl(I) complexes TlL and TlL′ [L = {N(SiMe3)C(Ph)}2CH, L′ = {N(C6H3Pri2-2,6)C(H)}2CPh].

Graphical abstract: Synthesis and characterisation of two monomeric crystalline thallium(i) β-diketiminates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B413666G
Article type
Communication
Submitted
07 Sep 2004
Accepted
15 Nov 2004
First published
15 Dec 2004

Chem. Commun., 2005, 752-754

Permissions

Request permissions

Synthesis and characterisation of two monomeric crystalline thallium(I) β-diketiminates

Y. Cheng, P. B. Hitchcock, M. F. Lappert and M. Zhou, Chem. Commun., 2005, 752 DOI: 10.1039/B413666G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements