Issue 3, 2005

Meridional bicyclometalation with iron: a novel way of forming dianionic [C,N,C]-ligands

Abstract

Bicyclometalation of aromatic substrates containing imine anchoring groups is achieved with a dimethyliron complex at −70 °C; azadiene systems undergo a regiospecific activation of 1,4-CH/N interchanged C–H bonds which may be aromatic or vinylic.

Graphical abstract: Meridional bicyclometalation with iron: a novel way of forming dianionic [C,N,C]-ligands

Supplementary files

Article information

Article type
Communication
Submitted
02 Sep 2004
Accepted
12 Oct 2004
First published
30 Nov 2004

Chem. Commun., 2005, 381-382

Meridional bicyclometalation with iron: a novel way of forming dianionic [C,N,C]-ligands

H. Klein, S. Camadanli, R. Beck and U. Flörke, Chem. Commun., 2005, 381 DOI: 10.1039/B413409E

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