Issue 4, 2005
From the journal:

Chemical Communications

Molybdenum-catalyzed hydrostannations of allenylcarbinols†

Uli Kazmaier*a  and  Manuela Kleina  

* Corresponding authors

a Universität des Saarlandes, Institut für Organische Chemie, Saarbrücken, Germany
E-mail: u.kazmaier@mx.uni-saarland.de
Fax: 49 681 3022409
Tel: 49 681 3023409

Abstract

Allenylcarbinols undergo regioselective hydrostannation in the presence of MoBl3, a catalyst which was developed for the hydrostannation of propargyl alcohols and derivatives; allylstannanes are formed preferentially, which can easily be converted into allyl iodides.

Graphical abstract: Molybdenum-catalyzed hydrostannations of allenylcarbinols

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Article information

DOI
https://doi.org/10.1039/B413025A
Article type
Communication
Submitted
24 Aug 2004
Accepted
21 Oct 2004
First published
02 Dec 2004

Chem. Commun., 2005, 501-503

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Molybdenum-catalyzed hydrostannations of allenylcarbinols

U. Kazmaier and M. Klein, Chem. Commun., 2005, 501 DOI: 10.1039/B413025A

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