Polymeric building blocks containing terminal azide and alkyne functionalities are prepared via atom transfer radical polymerization (ATRP) and used to modularly synthesize block copolymers via 1,3-dipolar cycloaddition reactions, which are quantitative according to SEC measurements.
J. A. Opsteen and J. C. M. van Hest, Chem. Commun., 2005, 57 DOI: 10.1039/B412930J
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