The Michael-type addition of aliphatic (co)polyesters onto γ-acryloyloxy ε-caprolactone units is a very straightforward technique of functionalization and grafting, which is tolerant to a variety of functional groups and does not require intermediate protection/deprotection steps.
J. Rieger, K. Van Butsele, P. Lecomte, C. Detrembleur, R. Jérôme and C. Jérôme, Chem. Commun., 2005, 274 DOI: 10.1039/B411565A
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