Issue 7, 2005
From the journal:

Chemical Communications

Molecular recognition in a uradinyl-functionalized stable radical

Patrick Taylor,a   Paul M. Lahti,*a   Joseph B. Carrolla  and  Vincent M. Rotelloa  

* Corresponding authors

a Department of Chemistry, University of Massachusetts, Amherst, USA
E-mail: lahti@chem.umass.edu

Abstract

Stable radical 2-(6-uradinyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl (1) binds to hydrogen-bonding complement 2,6-di(propylamido)pyridine (DAP) in chloroform with Ka = 220 M−1 at 33 °C; ESI-MS shows not only 1∶DAP complementary dyad formation, but also 1∶(DAP)2 formation at higher concentrations of DAP.

Graphical abstract: Molecular recognition in a uradinyl-functionalized stable radical

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Article information

DOI
https://doi.org/10.1039/B411389F
Article type
Communication
Submitted
23 Jul 2004
Accepted
12 Oct 2004
First published
17 Dec 2004

Chem. Commun., 2005, 895-897

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Molecular recognition in a uradinyl-functionalized stable radical

P. Taylor, P. M. Lahti, J. B. Carroll and V. M. Rotello, Chem. Commun., 2005, 895 DOI: 10.1039/B411389F

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