Issue 3, 2005
From the journal:

Chemical Communications

Tetraarylethylene having two nitroxide groups: redox-switching of through-bond magnetic interaction by conformation change†

Akihiro Ito,a   Yoshiaki Nakano,a   Tatsuhisa Katob  and  Kazuyoshi Tanaka*a  

* Corresponding authors

a Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: a51053@sakura.kudpc.kyoto-u.ac.jp

b Department of Chemistry, Josai University, 1-1 Keyakidai, Sakado, Japan

Abstract

Reversible redox-switching of through-bond magnetic interaction has been achieved by conformation change of the tetraarylethylene moiety upon redox input: intramolecular magnetic interaction between two nitroxide groups is dead after oxidation, whereas it was alive before.

Graphical abstract: Tetraarylethylene having two nitroxide groups: redox-switching of through-bond magnetic interaction by conformation change

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Article information

DOI
https://doi.org/10.1039/B410858B
Article type
Communication
Submitted
16 Jul 2004
Accepted
03 Sep 2004
First published
29 Nov 2004

Chem. Commun., 2005, 403-405

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Tetraarylethylene having two nitroxide groups: redox-switching of through-bond magnetic interaction by conformation change

A. Ito, Y. Nakano, T. Kato and K. Tanaka, Chem. Commun., 2005, 403 DOI: 10.1039/B410858B

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