Issue 12, 2005

A model for two-electron mixed valence in metal–metal bonded dirhodium compounds

Abstract

We propose that two-electron mixed valency in bimetallic complexes possessing three bridging ligands results from a second-order Jahn–Teller instability of the redox-symmetric state.

Graphical abstract: A model for two-electron mixed valence in metal–metal bonded dirhodium compounds

Supplementary files

Article information

Article type
Communication
Submitted
02 Jul 2004
Accepted
16 Dec 2004
First published
28 Jan 2005

Chem. Commun., 2005, 1540-1542

A model for two-electron mixed valence in metal–metal bonded dirhodium compounds

T. G. Gray and D. G. Nocera, Chem. Commun., 2005, 1540 DOI: 10.1039/B410003D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements