Issue 11-12, 2004
From the journal:

Photochemical & Photobiological Sciences

Formation of radical cations of aziridines generated by laser flash photolysis

Carsten Gaebert,ac   Christian Siegner,ad   Jochen Mattay,*a   Marion Toubartzb  and  Steen Steenken*b  

* Corresponding authors

a Organische Chemie I, Universität Bielefeld, Universitätsstraße 25, Bielefeld, Germany
E-mail: mattay@uni-bielefeld.de

b Max-Planck-Institut für Bioanorganische Chemie, Stiftstraße 34-36, Mülheim/Ruhr, Germany

c Consortium für Elektrochemische Industrie GmbH, Zielstattstraße 20, München, Germany

d Plaut Consulting, Im Breitspiel 19, Heidelberg, Germany

Abstract

The radical cations of 1-butyl-trans-2,3-diphenyl aziridine (1), 1-butyl-2-phenyl aziridine (2), 1,2-diphenyl aziridine (3) and 1-(p-methoxyphenyl)-2-phenyl aziridine (4) were generated upon laser flash photolysis in aqueous and aqueous acetonitrile solutions by direct photoionisation as indicated by the broad absorption band of the solvated electron above 550 nm as well.

Graphical abstract: Formation of radical cations of aziridines generated by laser flash photolysis

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Article information

DOI
https://doi.org/10.1039/B410464A
Article type
Communication
Submitted
08 Jul 2004
Accepted
22 Sep 2004
First published
07 Oct 2004

Photochem. Photobiol. Sci., 2004,3, 990-991

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Formation of radical cations of aziridines generated by laser flash photolysis

C. Gaebert, C. Siegner, J. Mattay, M. Toubartz and S. Steenken, Photochem. Photobiol. Sci., 2004, 3, 990 DOI: 10.1039/B410464A

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