Issue 7, 2004
From the journal:

Photochemical & Photobiological Sciences

Biradical to biradical rearrangement via 1,3-H atom transfer in photocycloisomerizations of 4-pent-4-enylcyclohex-2-enones

Lars Meyera  and  Paul Margaretha*a  

* Corresponding authors

a Institute of Organic Chemistry, University of Hamburg, D-20146 Hamburg, Germany

Abstract

An unprecedented ‘carbonyl-O-assisted’ 1,3-H atom transfer from a CH2 group to a primary alkyl radical center in 1,4-biradicals, formed in a crossed addition mode in the photocycloisomerization of 4-pent-4-enylcyclohex-2-enones, is discussed.

Graphical abstract: Biradical to biradical rearrangement via 1,3-H atom transfer in photocycloisomerizations of 4-pent-4-enylcyclohex-2-enones

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Article information

DOI
https://doi.org/10.1039/B403724C
Article type
Paper
Submitted
10 Mar 2004
Accepted
19 May 2004
First published
27 May 2004

Photochem. Photobiol. Sci., 2004,3, 684-688

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Biradical to biradical rearrangement via 1,3-H atom transfer in photocycloisomerizations of 4-pent-4-enylcyclohex-2-enones

L. Meyer and P. Margaretha, Photochem. Photobiol. Sci., 2004, 3, 684 DOI: 10.1039/B403724C

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