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Issue 3, 2004
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Palladium-catalyzed addition of disulfides and diselenides to alkynes under solvent free conditions

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Abstract

An efficient methodology was developed for performing palladium-catalyzed E–E (E = S, Se) bond addition to alkynes under solvent free conditions. Compared to reaction in solvent significant enhancement of reaction rate, improved efficiency and remarkable catalyst stability were observed under solvent free conditions. The addition reactions were carried out with high stereoselectivity and yields in a short reaction time.

Graphical abstract: Palladium-catalyzed addition of disulfides and diselenides to alkynes under solvent free conditions

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Publication details

The article was received on 10 Oct 2003, accepted on 16 Dec 2003 and first published on 19 Dec 2003


Article type: Communication
DOI: 10.1039/B312471A
Citation: Org. Biomol. Chem., 2004,2, 284-287
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    Palladium-catalyzed addition of disulfides and diselenides to alkynes under solvent free conditions

    V. P. Ananikov and I. P. Beletskaya, Org. Biomol. Chem., 2004, 2, 284
    DOI: 10.1039/B312471A

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