Issue 16, 2004
From the journal:

Organic & Biomolecular Chemistry

Inclusion by a fluorenyl host with volatile guests: structures, thermal stability and kinetics†

Mino R. Caira,a   Tanya le Roex,a   Luigi R. Nassimbeni,*a   John A. Ripmeesterb  and  Edwin Weberc  

* Corresponding authors

a Department of Chemistry, University of Cape Town, Rondebosch 7701, South Africa
E-mail: xrayluigi@science.uct.ac.za
Fax: +27-21-6854580
Tel: +27-21-6502569

b Steacie Institute for Molecular Sciences, National Research Council of Canada, 100 Sussex Drive, Ottawa, Ontario, Canada

c Institut für Organische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Strasse 29, D-09596 Freiberg/Sachs., Germany

Abstract

The structures of the inclusion compounds formed by the host H = 9,9′-(biphenyl-4,4′-diyl)bis(fluoren-9-ol) with N,N-dimethylacetamide (H·2DMA and H·4DMA), 1,4-dioxane (H·3DIOX), methyl ethyl ketone (H·2MEK), as well as that of the apohost have been elucidated. The compounds were characterised by thermal analysis and solid state NMR, and the kinetics of desorption of H·4DMA, H·2DMA and H·3DIOX have been examined.

Graphical abstract: Inclusion by a fluorenyl host with volatile guests: structures, thermal stability and kinetics

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Article information

DOI
https://doi.org/10.1039/B400721B
Article type
Paper
Submitted
16 Jan 2004
Accepted
29 Mar 2004
First published
16 Jul 2004

Org. Biomol. Chem., 2004,2, 2299-2304

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Inclusion by a fluorenyl host with volatile guests: structures, thermal stability and kinetics

M. R. Caira, T. le Roex, L. R. Nassimbeni, J. A. Ripmeester and E. Weber, Org. Biomol. Chem., 2004, 2, 2299 DOI: 10.1039/B400721B

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