Issue 12, 2004
From the journal:

New Journal of Chemistry

View from the bridge: a pseudo-Jahn–Teller approach to transition metal hydrosilane complexes†

Martin J. Paterson,a   Nicholas P. Chattertonb  and  G. Sean McGradyc  

a Department of Chemistry, Imperial College London, Exhibition Road, London, UK

b Departement de Recherche Fondamentale sur la Matière Condensée, CEA-Grenoble, Grenoble, Cedex 09, France

c Department of Chemistry, University of New Brunswick, Fredericton NB, Canada
E-mail: smcgrady@unb.ca

Abstract

The model complex [Cp(CO)2Mn(SiH4)] has been studied by time-dependent DFT methods: hence, it is shown to be unstable with respect to a pseudo-Jahn–Teller distortion which brings an equatorial Si–H moiety into contact with the Mn centre.

Graphical abstract: View from the bridge: a pseudo-Jahn–Teller approach to transition metal hydrosilane complexes

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Article information

DOI
https://doi.org/10.1039/B412371A
Article type
Letter
Submitted
11 Aug 2004
Accepted
26 Oct 2004
First published
18 Nov 2004

New J. Chem., 2004,28, 1434-1436

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View from the bridge: a pseudo-Jahn–Teller approach to transition metal hydrosilane complexes

M. J. Paterson, N. P. Chatterton and G. Sean McGrady, New J. Chem., 2004, 28, 1434 DOI: 10.1039/B412371A

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