Issue 12, 2004
From the journal:

New Journal of Chemistry

Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: their use for hydrogenolysis-free hydrogenation of olefins†

Jean Le Bras,a   Deb Kumar Mukherjee,a   Sara González,b   Mar Tristany,b   Benjamin Ganchegui,a   Marcial Moreno-Mañas,b   Roser Pleixats,b   Françoise Hénina  and  Jacques Muzart*a  

* Corresponding authors

a Laboratoire Réactions Sélectives et Applications (CNRS UMR 6519), Université de Reims Champagne-Ardenne, BP 1039, Reims cedex 2, France

b Department of Chemistry, Universitat Autonoma de Barcelona, Cerdanyola, Barcelona, Spain

Abstract

Carbon-carbon double bonds have been selectively hydrogenated at room temperature in the presence of benzyloxy groups using an atmospheric pressure of hydrogen, toluene or [bmim]PF6 as the solvent and palladium nanoparticles stabilized with tetrabutylammonium bromide. The system [bmim]PF6/palladium nanoparticles can be recycled without noticeable decrease of activity.

Graphical abstract: Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: their use for hydrogenolysis-free hydrogenation of olefins

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Article information

DOI
https://doi.org/10.1039/B409604E
Article type
Paper
Submitted
23 Jun 2004
Accepted
17 Sep 2004
First published
16 Nov 2004

New J. Chem., 2004,28, 1550-1553

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Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: their use for hydrogenolysis-free hydrogenation of olefins

J. Le Bras, D. K. Mukherjee, S. González, M. Tristany, B. Ganchegui, M. Moreno-Mañas, R. Pleixats, F. Hénin and J. Muzart, New J. Chem., 2004, 28, 1550 DOI: 10.1039/B409604E

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