Synthesis, spectroscopic properties, and electrochemistry of heteroleptic rare earth double-decker complexes with phthalocyaninato and meso-tetrakis (4-chlorophenyl)porphyrinato ligands†
Abstract
A series of fourteen heteroleptic (phthalocyaninato)(porphyrinato) rare earth(III) double-decker complexes, [MIII(Pc)(TClPP)]
[M = Y, La–Lu except Ce and Pm; Pc = phthalocyaninate; TClPP = meso-tetrakis(4-chlorophenyl)porphyrinate] has been prepared by base-promoted