Issue 3, 2004
From the journal:

New Journal of Chemistry

Synthesis and structural studies (1H, 13C, 31P NMR and X-ray) of new C-bonded cyclotriphosphazenes with heterocyclic substituents from novel phosphinic acid derivatives

Virginie Vicente,a   Alain Fruchier,a   Marc Taillefer,a   Corinne Combes-Chamalet,a   Ian J. Scowen,b   Françoise Plénata  and  Henri-Jean Cristau*a  

* Corresponding authors

a Laboratoire de Chimie Organique (CNRS UMR. 5076), E. N. S. C. M., 8 rue de l'Ecole Normale, Montpellier cedex 5, France
E-mail: cristau@cit.enscm.fr and taillefe@cit.enscm.fr
Fax: +33 (0)4 67 14 43 19
Tel: +33 (0)4 67 14 43 12

b Chemical and Forensic Sciences, University of Bradford, Bradford, UK
E-mail: i.scowen@Bradford.ac.uk
Fax: +44 (0)7769 886722
Tel: +44 (0)7769 886722

Abstract

Three new C-bonded cyclotriphosphazenes, [N3P3(2-thienyl)6], 2, [N3P3(3-thienyl)6], 4, and [N3P3(3,3′-bithienyl-2,2′-ylene)3], 6, have been prepared by two new synthetic procedures and are the first examples of non-spiro and trispirocyclotriphosphazene derivatives composed of thiophene and 3,3′-dithiophene substituents, respectively. Their 1H, 13C and 31P NMR parameters are given. The solid state structures of 2, 4 and 6 have been determined by X-ray crystallography.

Graphical abstract: Synthesis and structural studies (1H, 13C, 31P NMR and X-ray) of new C-bonded cyclotriphosphazenes with heterocyclic substituents from novel phosphinic acid derivatives

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B311046J
Article type
Paper
Submitted
10 Sep 2003
Accepted
24 Oct 2003
First published
13 Feb 2004

New J. Chem., 2004,28, 418-424

Permissions

Request permissions

Synthesis and structural studies (1H, 13C, 31P NMR and X-ray) of new C-bonded cyclotriphosphazenes with heterocyclic substituents from novel phosphinic acid derivatives

V. Vicente, A. Fruchier, M. Taillefer, C. Combes-Chamalet, I. J. Scowen, F. Plénat and H. Cristau, New J. Chem., 2004, 28, 418 DOI: 10.1039/B311046J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements