Issue 4, 2004

Synthesis and crystal structure of trinuclear carboxylate complexes M33-O)(CF3COO)6L3

Abstract

Oxocarboxylate complexes of 3d metals containing a trinuclear neutral or cationic [M33-O)(CF3COO)6L3]0,+ unit (M = Cr, Fe; L = MeCOOH, H2O, CF3COO, THF) were obtained by electrolytic dissolution of a metal in CF3COOH or by a reaction of a metal (or its compound) with CF3COOH; the crystal structures of three complexes were studied by single X-ray crystallography.

Article information

Article type
Communication
Submitted
02 Jun 2004

Mendeleev Commun., 2004,14, 141-143

Synthesis and crystal structure of trinuclear carboxylate complexes M33-O)(CF3COO)6L3

T. Yu. Glazunova, A. I. Boltalin and S. I. Troyanov, Mendeleev Commun., 2004, 14, 141 DOI: 10.1070/MC2004v014n04ABEH001953

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