According to the B3LYP calculations, nitrous oxide, the product of N2 oxidation by peroxo vanadium complexes, easily adds to the V=O bond to form hyponitrite, which undergoes further oxidation.
Is nitrous oxide an intermediate product in the oxidation of molecular nitrogen by vanadium peroxo complexes?
A. F. Shestakov and N. S. Emel'yanova, Mendeleev Commun., 2004, 014, 117 DOI: 10.1070/MC2004v014n03ABEH001829
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