Issue 17, 2004
From the journal:

Journal of Materials Chemistry

Supercritical CO2 modified organic ionic plastic crystals

Steven J. Pas,†a   Jim Efthimiadis,b   Jennifer M. Pringle,b   Maria Forsythb  and  Douglas R. MacFarlane*a  

* Corresponding authors

a School of Chemistry, Monash University, Clayton, Victoria, Australia
E-mail: douglas.macfarlane@sci.monash.edu.au
Fax: +61-3-9905-4597
Tel: +61-3-9905-4540

b School of Physics and Materials Engineering, Monash University, Clayton, Victoria, Australia
E-mail: maria.forsyth@spme.monash.edu.au
Fax: +61-3-9905-4940
Tel: +61-3-9905-4939

Abstract

The treatment of an organic ionic plastic crystal electrolyte N-methyl-N-ethylpyrrolidinium tetrafluoroborate (P1,2BF4) with supercritical CO2 resulted in a substantial increase in ionic conductivity, especially in the more highly ordered solid phases of the material, and also stabilised the most ordered phase to lower temperatures.

Graphical abstract: Supercritical CO2 modified organic ionic plastic crystals

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Article information

DOI
https://doi.org/10.1039/B407624A
Article type
Communication
Submitted
19 May 2004
Accepted
07 Jul 2004
First published
23 Jul 2004

J. Mater. Chem., 2004,14, 2603-2605

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Supercritical CO2 modified organic ionic plastic crystals

S. J. Pas, J. Efthimiadis, J. M. Pringle, M. Forsyth and D. R. MacFarlane, J. Mater. Chem., 2004, 14, 2603 DOI: 10.1039/B407624A

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