Issue 22, 2004
From the journal:

Dalton Transactions

First transition-metal complexes of S[double bond, length as m-dash]P(NHBut)3†

Konstantin A. Rufanov,*a   Burkhard Ziemera  and  Manfred Meisela  

* Corresponding authors

a Institut für Chemie, Humboldt Universität zu Berlin, Brook-Taylor-Strasse 2, Berlin, Germany
E-mail: k_rufanov@gmx.net
Fax: + 49 30 20937468
Tel: +49 30 20937368

Abstract

The first transition-metal (RhI, MoVI, NiII) complexes of S[double bond, length as m-dash]P(NHBut)31 have been synthesized via metathetical reactions of mono-lithiated 1 and [Rh(CO)2Cl]2, (ButN)2MoCl2(dme) and NiBr2(dme). Surprisingly in the molecular structure of the NiII-complex both hard–soft (N,S) and hard–hard (N,N′) chelation modes of 1 are realized.

Graphical abstract: First transition-metal complexes of S [[double bond, length as m-dash]] P(NHBut)3

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Article information

DOI
https://doi.org/10.1039/B413555E
Article type
Communication
Submitted
02 Sep 2004
Accepted
07 Oct 2004
First published
18 Oct 2004

Dalton Trans., 2004, 3808-3809

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First transition-metal complexes of S[double bond, length as m-dash]P(NHBut)3

K. A. Rufanov, B. Ziemer and M. Meisel, Dalton Trans., 2004, 3808 DOI: 10.1039/B413555E

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