Photolytic and thermal properties of a new series of intramolecular bridged alkyl cobaloxime complexes
Abstract
The photolytic kinetic properties of a new series of intramolecular bridged alkyl cobaloxime complexes Br(O–C3H6-(dmgH))(dmgH))CoIII
(2), [H2O(O–C3H6-(dmg))(dmgH2)]CoIII[ClO4
(3), ]Py(O–C3H6-(dmg))(dmgH2)[CoIII]ClO4
(4), [Bzm(O–C3H6-(dmg))(dmgH2)]CoIII[ClO4
(5) and ]Im(O–C3H6-(dmg))(dmgH2)[CoIII]ClO4
(6) and their precursor aqua-(3-bromopropyl)cobaloximes (1) were investigated by