Diazenide and hydrazide(2−) derivatives of the [Re(CO)3]+ core
Abstract
Reaction of [ReBr3(CO)3]2− with aryldiazonium salts gives the Re(III) diazenide complexes [ReBr2(NNC6H4R-4)(CO)2]−. The attachment of a PhNHCS tethering group to
* Corresponding authors
a Institute of Inorganic Chemistry, University of Zürich, Winterhurerstrasse 190, Zürich, Switzerland
b Chemical Crystallography Laboratory, University of Oxford, 12 Mansfield Road, Oxford, UK
c
Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford, UK
E-mail:
jon.dilworth@chem.ox.ac.uk
Fax: 01865-272690
Tel: 01865-285151
Reaction of [ReBr3(CO)3]2− with aryldiazonium salts gives the Re(III) diazenide complexes [ReBr2(NNC6H4R-4)(CO)2]−. The attachment of a PhNHCS tethering group to
R. Alberto, A. R. Cowley, J. R. Dilworth, P. S. Donnelly and J. Pratt, Dalton Trans., 2004, 2610 DOI: 10.1039/B407708C
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